Mühendislik Fakültesi / Faculty of Engineering

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A Critical Assessment Of The Design Displacements Of Friction Pendulum Systems
(SOIL DYNAMICS AND EARTHQUAKE ENGINEERING, 2024-02) Alici, F. Soner; Sucuog, Haluk; Ozcamur, Ugurcan
The equivalent linear static procedure suggested in seismic codes for determining the maximum displacements of seismic isolation systems is evaluated comprehensively for friction pendulum isolators with respect to the benchmark nonlinear response history analysis procedure for a set of radii of curvature and coefficients of friction. A large set of selected and scaled near field ground motions recorded on stiff and soft soils are employed in comparative evaluations. It has been observed that equivalent linear static procedure significantly overestimates the maximum isolator displacements for all practical combinations of radius of curvature and friction coefficient. Overestimation is larger for ground motions on soft soils. Alternatively, a practical description of inelastic displacement spectra is introduced where the hazard is defined in terms of the 1-second spectral acceleration accounting for the seismicity and soil class of the site, and friction pendulum isolation systems are characterized by their radius of curvature and nominal friction coefficient. Employing the proposed design spectra in design and production may lead to significant reductions of the isolator sizes. Moreover, realistic estimation of maximum isolator displacements also leads to realistic estimation of isolator stiffness, as well as the internal design forces of both the isolation system and the superstructure through response spectrum analysis under design spectrum.
A Dss Development Study For Document Distribution Networks For Preparing Autonomous Vehicle-Integrated Distribution Systems
(DECISION, 2024-12) Derya, Tusan; Ic, Yusuf Tansel; Erbay, Mehmet Dogan; Konuk, Kubra; Fidan, Nihal
We propose a decision support system (DSS) to complete the tours of the routes of the traveler in charge of document distribution in the least amount of time for the document distribution task of a university to prepare autonomous vehicle-integrated distribution systems. A mathematical model-based decision support system is developed to determine distribution routes that optimize the total distance to target locations and obtain optimal system conditions for use in the migration of autonomous distribution systems. The purpose is to find the shortest-cost tours to cover all or subsets of edges in a network. Documents are shared and distributed by travelers to other related locations. Soon after, travelers will be replaced by autonomous vehicles. There are many application areas, such as newspapers and mail delivery systems. Therefore, the proposed model can be easily extended to other application areas, such as newspaper, cargo, and mail delivery systems, to construct autonomous vehicle-based systems.
A Fuzzy Computing Approach To Aggregate Expert Opinions Using Parabolic And Exparabolic Approximation Procedures For Solving Multi-Criteria Group Decision-Making Problems
(Başkent Üniversitesi Mühendislik Fakültesi, 2024-03-02) Ic, Yusuf Tansel
Triangular fuzzy numbers (TFNs) are widely used for selection problems to determine expert opinions using linguistic expressions. Some aggregation procedures are developed to determine expert opinions more accurately. However, there is a need for a simple and more useful procedure to solve the selection problems more suitably. For this purpose, our study offers a triangular, exparabolic, and parabolic area calculation-based approximation approach for TFNs to aggregate the possible hedges (very and more or less) for TFNs. Hence, this aggregation procedure provides a tuning opportunity for classical TFN expressions to capture possible tuning processes to reflect the hesitancies of experts. The technique for order preferences by similarity to ideal solution (TOPSIS) method is applied in the two studies from extant literature, and suitable alternatives are determined as a result of the ranking process. Finally, a comparative analysis is presented to illustrate the efficiency of the proposed procedure. The conventional TOPSIS model's ranking scores are very close for exemplified examples (i.e., 0.5308, 0.4510, 0.4550 and 0.5304, 0.4626, 0.4940), but the proposed model's result has fluctuated for the same examples (i.e., 0.346, 0,669, 0,567 and 0.208, 0.991, 0.148). So, the main advantage of the proposed aggregation procedure is the alternative ranking scores separation capability analyzed with their linguistic diversification.
A Hybrid Monte Carlo Simulation Risk Model for Oil Exploration Projects
(MARINE POLLUTION BULLETIN, 2023) Balas, Egemen Ander
A new 3-D Hybrid Monte Carlo Simulation (MCS) Risk Model is proposed in this study. The wind, wave, current, climate change, and tsunami sub-models of the Three-Dimensional Hydrodynamic Transport and Water Quality Model HYDROTAM-3D are interrelated with MCS, to obtain probability distributions for the simulation of environmental conditions. This is the only model that can incorporate the tsunami, storm, and sea level rise risks in oil exploration projects. The spill risk index (SRI) of 50 blue barrels spilled due to a blowout from the rig/port during fuel supply was circa 1 ton/ship as Tier I with an average annual occurrence probability of 1.0 x 10-6. The discharge of 4000 bbls for 6 h was modeled, resulting in the SRI of 546 metric tons from the riser blowout with SRI = 0.2 per meter, indicating a Tier II risk. The mean arrival time of this spill was found by MCS as 145 min.
A Multi-Objective Optimization Framework for Functional Arrangement in Smart Floating Cities
(EXPERT SYSTEMS WITH APPLICATIONS, 2024) Kirimtat, Ayca; Tasgetiren, M. Fatih; Krejcar, Ondrej; Buyukdagli, Ozge; Maresova, Petra
Before the terms "smart city" and "floating city" were introduced, the world's population had increased and land shortage across the world was already widely recognized. As a first challenge, the previous studies have developed the concept of a smart city as a creative answer, following that, several scientists proposed the floating city concept in the literature as a solution to the increased sea levels. Moreover, engineers, architects, and designers deal with city planning, for smart and floating settlements as a difficult design challenge, and evolutionary algorithms could be employed to address this complex problem by optimizing residents' needs. As a continuation of our previous studies on this topic, this time, we develop a multi-objective continuous genetic algorithm with differential evolution (DE) mutation strategy (MO_CGADE) and a multi-objective ensemble differential evolution algorithm (MO_EDE) to solve the problem on hand. Then, we compare the performance of the MO_CGADE and MO_EDE algorithms with the non-dominated sorting genetic algorithm (NSGAII) to maximize two conflicted objective functions, namely, scenery, and walkability in the proposed smart floating city model created in the Grasshopper Algorithmic Modeling Environment. The parametric model that we create in the Grasshopper software includes 64 decision variables, area constraints and objective functions to be optimized by MO_CGADE, MO_EDE, and NSGAII algorithms. Computational results show that MO_CGADE and MO_EDE algorithms generate better Pareto ranking results than the traditional NSGAII algorithm in terms of cardinality, distribution spacing, and coverage metrics.
A Performance Evaluation Study of Thin-Wall Tube Design in the Front Bumper Uses The Altered TOPSIS-Rank Order Clustering Algorithm-Integrated Approach
(MULTISCALE AND MULTIDISCIPLINARY MODELING EXPERIMENTS AND DESIGN, 2024)
Abstract The rising growth of the economy in developing countries led to a significant increase in the number of vehicles on the roads. The number of vehicles in road transport is also increasing significantly due to the increase in automobile ownership due to the increase in city populations. As a result of this increase, there is an increase in traffic accidents. For this reason, automobile manufacturers make significant efforts to develop lighter and more robust bumpers. Also, they used performance measurement studies for the thin-walled bumpers. The motivation of the study is based on the examines the dynamic performance of thin-walled bumpers within the impact of both oblique and axial compression. The crash performance of thin-wall tubes is analyzed based on factors such as speed, mass, and cross-section geometries. We developed a new rank order clustering (ROC) algorithm that integrated altered technique for order preferences by similarity to ideal solution (A-TOPSIS) method-based comparative analysis to determine the best thin-wall tube among the alternatives. For the first time in the literature, the A-TOPSIS results-integrated ROC algorithm is proposed to obtain the best tube profiles considering different expectations from their performance according to the determined criteria.Please check and confirm the edi t in the article title.OK.Please confirm if the author names are presented accurately and in the correct sequence (given name, middle name/initial, family name). Author 2 Given name: [Yusuf Tansel] Last name [Ic] and Author 4 Given name: [Bekir Batuhan] Last name [Sagol]. Also, kindly confirm the details in the metadata are correct.OK
Accelerating The Environmental Biodegradation Of Poly-3-Hydroxybutyrate (Phb) Via Plasma Surface Treatment
(BIORESOURCE TECHNOLOGY REPORTS, 2024-09-02) Akdogan, Ebru; Sirin, Hasret Tolga; Sahal, Gulcan; Deniz, Zulkuf; Kaya, Ayberk; Serdaroglu, Dilek Cokeliler
The surface of poly-3-hydroxybutyrate (PHB) was modified using a low-pressure plasma system with air as the process gas to accelerate its biodegradation rate in soil. The water contact angle of PHB was reduced from 98 degrees to 57 degrees after plasma treatment, rendering the surface hydrophilic and also induced an increase in the surface free energy. Etching on the surface was observed after the plasma treatment without a significant change in the surface crystallinity. AFM imaging showed that the plasma treatment increased the surface roughness by about 10 folds and created diverse surface structures. The soil burial test showed an approximately 1.5-fold increase in the biodegradation rate for the plasma-treated sample. Initial microbial attachment and biofilm formation were higher on the modified surface. This study demonstrated that the surface morphology created by plasma treatment promoted initial colonization and subsequent biofilm formation on the PHB surface, facilitating and accelerating its biodegradation in soil.
An Algorithmic Approach To Portfolio Construction: A Turkish Stock Market Case
(BORSA ISTANBUL REVIEW, 2024-11) Gulsen, Mehmet; Yildiz, Burak
The goal of building a diversified portfolio is to mitigate risks and manage risk-reward tradeoffs. Diversification is also crucial for ensuring the long-term success of a portfolio. Although passive investment has been on the rise in most developed markets, it has not gained wider acceptance in some emerging markets, such as T & uuml;rkiye. This study proposes an approach to construct a diversified portfolio that serves as a passive investment tool in the context of the Turkish stock market. Despite the long history of equity markets in T & uuml;rkiye, almost all available passive investment alternatives are prohibitively expensive, unlike those in developed markets. We design a simple methodology that addresses the essential components of building a successful portfolio while avoiding excessive fees. Additionally, we propose a dynamic balancing strategy that algorithmically adjusts the weight of each stock in the portfolio. We test this approach with historical data, demonstrating that it can achieve reasonable returns with minimal effort. Even when its performance does not beat the benchmark, the percentage deviation is still below the management fees charged for alternative investments.
An Effective Optimization Method for Integrated Scheduling of Multiple Automated Guided Vehicle Problems
(TSINGHUA SCIENCE AND TECHNOLOGY, 2024-10) Sang, Hongyan; Li, Zhongkai; Tasgetiren, M. Fatih
Automated Guided Vehicle (AGV) scheduling problem is an emerging research topic in the recent literature. This paper studies an integrated scheduling problem comprising task assignment and path planning for AGVs. To reduce the transportation cost of AGVs, this work also proposes an optimization method consisting of the total running distance, total delay time, and machine loss cost of AGVs. A mathematical model is formulated for the problem at hand, along with an improved Discrete Invasive Weed Optimization algorithm (DIWO). In the proposed DIWO algorithm, an insertion-based local search operator is developed to improve the local search ability of the algorithm. A staggered time departure heuristic is also proposed to reduce the number of AGV collisions in path planning. Comprehensive experiments are conducted, and 100 instances from actual factories have proven the effectiveness of the optimization method.
Assessing the Shield Termination Approaches in Aircraft Wiring to Against the Lightning Indirect Effects
(JOURNAL OF POLYTECHNIC-POLITEKNIK DERGISI, 2024) Atalay, Emre; Tuncer, Ahmet Turgut)
Lightning is a natural phenomenon where high voltages and currents suddenly discharge. It can be caused by clouds themselves, clouds between them, or clouds near the earth. Aircraft are at risk of being struck by lightning and there is currently no way to prevent this from happening. Instead, efforts are being made to protect by reducing the effects of lightning. Metal structures in aircraft form a Faraday cage which helps in preventing lightning currents from entering the aircraft. However, composite structures, which are becoming more prevalent in the aviation sector, are less efficient in doing so compared to metals. Additionally, openings such as windows in the aircraft can break the Faraday cage and allow strong electromagnetic fields to penetrate. Hence, all equipment used on board the aircraft must be adequately qualified and lightning-proof. The most popular technique used to reduce the indirect effects of lightning on electronics is cable shielding. In this study, various shielding termination techniques for their effectiveness against indirect effect of lightning examined and it is found that utilizing a 360 degrees backshell termination technique provided to be highly effective, providing protection of nearly 3 dB. The results obtained from the experiments are compared with simulation results and previous studies.
Categorization Of Alzheimer's Disease Stages Using Deep Learning Approaches With Mcnemar's Test
(Başkent Üniversitesi Mühendislik Fakültesi, 2024-03-13) Sener, Begum; Acici, Koray; Sumer, Emre
Early diagnosis is crucial in Alzheimer's disease both clinically and for preventing the rapid progression of the disease. Early diagnosis with awareness studies of the disease is of great importance in terms of controlling the disease at an early stage. Additionally, early detection can reduce treatment costs associated with the disease. A study has been carried out on this subject to have the great importance of detecting Alzheimer's disease at a mild stage and being able to grade the disease correctly. This study's dataset consisting of MRI images from the Alzheimer's Disease Neuroimaging Initiative (ADNI) was split into training and testing sets, and deep learning -based approaches were used to obtain results. The dataset consists of three classes: Alzheimer's disease (AD), Cognitive Normal (CN), and Mild Cognitive Impairment (MCI). The achieved results showed an accuracy of 98.94% for CN vs AD in the one vs one (1 vs 1) classification with the EfficientNetB0 model and 99.58% for AD vs CNMCI in the one vs All (1 vs All) classification with AlexNet model. In addition, in the study, an accuracy of 98.42% was obtained with the EfficientNet121 model in MCI vs CN classification. These results indicate the significant potential for mild stage Alzheimer's disease detection of Alzheimer's disease. Early detection of the disease in the mild stage is a critical factor in preventing the progression of Alzheimer's disease. In addition, a variant of the non -parametric statistical McNemar's Test was applied to determine the statistical significance of the results obtained in the study. Statistical significance of 1 vs 1 and 1 vs all classifications were obtained for EfficientNetB0, DenseNet, and AlexNet models.
Cu2znsns4 Films Prepared By A Hybrid Pvd Deposition System: A Multi-Layered Graphitic Carbon Intermediate Layer At The Mo/Czts Interface
(JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS, 2024-11) Akcay, Neslihan; Yildirim, Ali Riza; Kesik, Deha; Gremenok, Valery F.; Ozcelik, Suleyman; Ceylan, Abdullah
We report the insertion of a new intermediate layer, a multi-layered graphitic carbon (MLGC), at Mo/CZTS interface and its impact on the structural and morphological characteristics of the back interface and absorber. MLGC was synthesized directly on Mo-coated SLG under a gas mixture flow of H2/CH4 at 550 degrees C via PECVD for 3 and 5 h. CZTS precursors were prepared on SLG/Mo and MLGC-coated SLG/Mo in a hybrid physical vapor deposition system, including evaporation and sputtering techniques, then subjected to sulfurization at 550 degrees C. The sheet resistance of back contact, microstructural parameters of the absorbers, the distributions of C and constituent elements were investigated. The diffraction peaks of the hexagonal Mo2C indicated the reaction between the C and Mo before the MLGC's growth. Raman analysis confirmed the formation of the MLGC during the long deposition time after the Mo2C formation. With the addition of MLGC, the sheet resistance of the back contact decreased from 2 to 0.5 ohm/sq, and the crystallite size of the absorbers improved. Raman spectra from the interface exhibited that MoS2 peaks' intensities significantly reduced with increasing the growth time. This implied that the 5 h-deposited MLGC was more effective in blocking the reaction between Mo and S. The absorbers with the MLGC had more uniform surface morphologies, densely packed grains, and fewer secondary phases. FIB analysis revealed the separation of the absorber with the 5 h-deposited MLGC into two parts due to C impurity. More C diffusion into the absorber for this sample was confirmed by SIMS.
Design and Implementation of Drive and Control System for Ultrasonic Motor over Power Line Communication
(ELECTRIC POWER COMPONENTS AND SYSTEMS, 2024-04-20) Daldal, Nihat; Aytar, Oktay; Bekiroglu, Erdal; Bal, Gungor
In this study, remote control application of an ultrasonic motor (USM) has been achieved over the power line communication (PLC) system. Fast, practical, affordable and effective operating mode is essential for the USM. This study aimed to develop an original, efficient, effective and economical method. Drive and control of USM control has been succeeded with the developed PLC control system. A two-phase high-frequency inverter, a power line transmitter, and a power line receiver circuits have been designed to drive and control of the ultrasonic motor. Required measurements are acquired from the power line to select the most suitable communication frequency and coupling circuit impedance for the PLC system. For the communication frequency and impedance value measurements the receiver and the transmitter circuits have been designed. The PLC-controlled system has been tested for different operating conditions of the ultrasonic motor. USM control has been accomplished over the existing power line without using extra cables and interfaces for communication. The obtained results show that the PLC-controlled system is practical, reliable, cost-effective, and feasible for the remote control of the USM. This research contributes a new and essential perspective for the PLC-based remote control studies in addition to the USM drive and control strategies.
Determination of Circuit Parameters in Domestic Induction Heaters by Analytical Solution Method
(Başkent Üniversitesi Mühendislik Fakültesi, 2024-04-04) Unal, Kenan; Oncu, Selim; Tuncer, Ugur; Bal, Gungor
Domestic induction heaters provide efficient, fast, and safe heating. Variable circuit parameters in domestic induction heaters show different characteristics depending on the type of parts used for heating and the area they cover on the heating coil. For this reason, resonant frequency, maximum inverter current, and quality factor parameters of the induction heaters also change. In this study, the tests of the domestic induction heater circuit with series resonant inverter were carried out with various of workpieces diameters. The resonant frequency and maximum inverter current parameters obtained from the experimental studies, curve fitting process was performed in the MATLAB and a function on related with heater parameters was derived. By using the obtained functions, the resonant frequency and maximum inverter current of the materials in the workpieces with intermediate diameters were calculated with high accuracy and compared experimentally. Analytical calculations and experimental results confirmed each other with an accuracy and it was shown that induction heater circuit parameters could also be calculated by analytical solution method.
Effect of Microwave-Vacuum Drying on the Physicochemical Properties of a Functional Tomato Snack Bar
(JOURNAL OF THE SCIENCE OF FOOD AND AGRICULTURE, 2024) Gul, Muhammed Rasim; Ince, Alev Emine; Ozel, Baris; Uslu, Aymelek Kubra; Cetin, Melis; Mentes, Duygu; Sumnu, Servet Gulum; Oztop, Mecit Halil
BACKGROUND: Tomato is an indispensable ingredient of the Mediterranean diet. Reformulation of traditional Mediterranean products to increase the adherence of consumers is becoming popular. In this study, a tomato snack bar enriched with olive powder and pea protein was developed by using microwave-vacuum drying. Formulations also included tomato powder (TP) and low-methoxylated pectin (LMP) as a structuring agent. RESULTS:The moisture content of microwave-vacuum-dried samples varied in the range 13.6-19.8% and water activity (a(w)) values were similar to 0.6. LMP and TP concentrations affected the color of microwave-vacuum-dried samples. However, the color mainly changed in conventionally dried samples due to browning. In microwave-vacuum-dried samples, lycopene content decreased with increasing LMP, but increased with increasing TP. Textural properties of microwave-vacuum-dried snack bars increased with increasing LMP and TP. CONCLUSION: Both texture and Fourier transform infrared spectroscopy results indicated that there was a network formation due to the contribution of protein and pectin; however, the type of interaction was highly dependent on the drying mechanism. Nuclear magnetic resonance relaxometry data showed that microwave-vacuum-dried samples had a more uniform water distribution. Besides its time and energy efficiency, microwave-vacuum drying improved the color and textural properties of tomato snack bars compared to conventionally dried ones. (c) 2023 The Authors. Journal of The Science of Food and Agriculture published by John Wiley & Sons Ltd on behalf of Society of Chemical Industry.
Ergodic Type Theorems Via Statistical Convergence
(FILOMAT, 2024) Oguz, Gencay
In the present paper we obtain some mean ergodic and uniform ergodic type theorems via statistical convergence in a Banach space. We prove, in this case that, the mean ergodic decomposition remains true. We also characterize statistical uniform ergodicity for an operator T is an element of B(X) under the condition st - lim(n )parallel to T-n parallel to/n = 0.
Exploring the Critical Risk Factors of Public-Private Partnership City Hospital Projects in Turkey
(BUILDINGS, 2024-03-14) Dogan Erdem, Tugba; Birgonul, Zeynep; Bilgin, Gozde; Akcay, Emre Caner
Governments face challenges in delivering essential public services due to their limited funds. This has led to an increasing reliance on the Public-Private Partnership (PPP) model, an alternative financing model involving a long-term collaboration between the private and public sectors to provide public services. Turkey, as a developing country facing financial limitations, has embraced the PPP model to address urgent public needs. Over the past decade, the Turkish Government has extensively utilized the PPP model, particularly in executing city hospital projects. However, investors have faced challenges in project execution due to various risk factors. Therefore, the main objective of this study is to explore the critical risk factors associated with PPP city hospital projects in Turkey. In this context, a comprehensive literature review was conducted to identify potential risks related to PPP city hospital projects. A questionnaire survey was implemented to assess the probability of occurrence and the severity of the impact of these risk factors. The collected data underwent analysis to determine the priority of these risk factors. The findings revealed that the top five most critical risk factors in PPP city hospital projects in Turkey are "foreign exchange rate fluctuations", "inflation rate volatility", "high finance costs", "fiscal issues", and "economic crises". Conversely, "unavailability of equipment" was identified as the least significant risk factor. The insights gained from this research can offer valuable guidance for prospective investors interested in participating in PPP city hospital projects in Turkey and other developing countries with similar conditions.
Fault Detection System For Paper Cup Machine Based On Real-Time Image Processing
(Başkent Üniversitesi Mühendislik Fakültesi, 2024-03-31) Aydin, Alaaddin; Guney, Selda
In the production of paper cups in industrial factories, it is tried to print high quality cups with less waste loss with the help of sensors and heating resistances mounted on the paper cup machine. In this study, a system that detects faulty products based on image processing and removes it by controlling the machine with servo motors, asynchronous motors and programmable logic controller (PLC) is designed. For fault product detection, classification has been performed using real-time Haarcascade algorithm and You Only Look Once (YOLO) algorithm which is a deep learning methods, and real-time object detection has been carried out using the OpenCv library. With this study, an effective faulty product detection and removing hardware system was realized by adapting artificial intelligence algorithms to a machine used in industry. Based on the results, a whole system can be applied to systems that involve removing a faulty product from a band in any production, packaging etc. facility is proposed. A hardware consisting of servo motors, asynchronous motors and PLC was designed to separate faulty cups from the existing paper cup production machine in this study. Then, a data set composed of 1068 images was created with images taken from the camera for faulty and faultless paper cups. Using this dataset, the effect of different deep learning methods on performance in the real-time system has been examined and successful results have been obtained. The optimal outcome was achieved, yielding a real-time application accuracy rate of 90.8% through the utilization of the Yolov5x architecture.
Fine-Tuning Sno2 Films: Unleashing Their Potential Through Deposition Temperature Optimization By Ultrasonic Spray Pyrolysis
(Başkent Üniversitesi Mühendislik Fakültesi, 2024-03-31) Sarica, Emrah; Ozcan, Hakan Bilal; Gunes, Ibrahim; Terlemezoglu, Makbule; Akyuz, Idris
In this study, the optimization of the deposition temperature, which directly affects the crystallinity, morphology, and electrical conductivity of SnO2 films deposited onto Corning Eagle XG glass substrates using the ultrasonic spray pyrolysis technique, was investigated to tailor their physical properties for various applications. Structural analyses revealed that the films had a tetragonal rutile structure, and while films deposited at lower temperatures exhibited a higher prevalence of (200) oriented planes, yet this decreased with an increase in deposition temperature. Morphological analyses showed that the films consisted of grains with octahedral shapes, and films deposited at lower temperatures were found to be more compact. The films had bandgap energy ranges between 3.96 eV and 4.02 eV. Hall effect measurements revealed that not only the carrier concentration decreased from 4.52 x 10(19) cm(-3) to 0.80 x 10(19) cm(-3), but the mobility also decreased from 23.32 cm(2)/Vs to 12.85 cm(2)/Vs. Among all the films, it was noted that the films deposited at 350 degrees C had the highest figure of merit which is 12.3 x 10(-4) Omega(-1). It can be concluded that the changes underlying these variations are associated with structural and morphological changes depending on the substrate temperature. Also, significant results have been attained in applications where precise control over crystal structure and surface morphology is crucial.
Fluorine-Doped Tin Oxide Films Via Ultrasonic Spray Pyrolysis: Investigation Of Physical Properties Post-Annealing And Their Potential For Tco Applications
(MATERIALS TODAY COMMUNICATIONS, 2024-12) Gunes, Ibrahim; Sarica, Emrah; Bilgin, Vildan; Kucukarslan, Ayse; Ozder, Serhat
In this study, undoped tin oxide (SnO2) and fluorine (F)-doped SnO2 (FTO) films at various doping levels were deposited on glass substrates using the ultrasonic spray pyrolysis technique, followed by an annealing process applied to the films after deposition. In line with this, the study reveals the significant impact of the fluorine doping level optimization on certain physical properties such as the structural, optical, and electrical characteristics of the obtained films, and presents the consequences of the variation in these physical properties for adaptability in various optoelectronic applications. No diffraction peaks were observed in the X-ray diffraction patterns of the deposited films. After the annealing process, however, films with a polycrystalline form and a rutile tetragonal crystal structure were obtained. It was observed that the crystallization levels were better in films doped with 5 % and 10 % F. The optical band gap values of the films were determined to vary between 3.35 eV and 3.68 eV. Furthermore, it was found that with the increase in F doping level, the resistivity (ranging from 2.1 Omega cm to 43.5 Omega cm) and sheet resistance (ranging from 1.62x10(5) Omega/sq to 35.9x10(5) Omega/sq) values of the films decreased, while the figure of merit values (ranging from 0.12x10(-8) Omega(-1) to 67.1x10(-8) Omega(-1)) increased. Among all FTO films, it was revealed that films doped with 10 % F exhibited the highest optical transmittance, the lowest electrical resistivity, and the highest figure of merit values.